D

0 5000 10000 15000 20000 24000 300DO time, s
500 1000 1500 2000 2500 3000 time, s

Fig. 19. Simulated kinetics curves of DNIC formation in mixtures of Fe2+, S-nitrosothiol and free thiol at various initial concentrations and rate constants. For certain starting concentrations of the reagents, the simulations predict oscillatory time dependence of the DNIC concentration. (From Ref. [19].)

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